我国首次发现的碳氢钠石
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    摘要:

    碳氢钠石是一种无水碱金属碳酸盐矿物,最初发现于美国的绿河盆地。一九八二年,在我国河南省泌阳凹陷首次发现。该矿物的化学成分是Na_2CO_3和NaHCO_3,分子式是:Na_2CO_3·3NaHCO_3。该矿物晶体呈板状,无色透明,主要产在重碳钠盐组成的碱矿层中。经测试确定,该矿物属二轴晶负光性,主折射率:Ng=1.531,Nm=1.524,Np=1.435,2V=31.45°;晶胞参:a=10.046,b=15.633,c=3.492,a=92°8′,β=95。42′,γ=108°34′;最强的粉晶衍射线有:3.70(35),2.97(100),2.67(41),2.213(60);主要的红外光谱吸收带是:2616,1692,1662,1359,1048,1018,839,677cm(-1)。据碳氢钠石的产状和共生组合特征,该矿物产于富钠,高P(CO2)的碳酸盐型内陆盐湖,是较高温度条件下快速蒸发的产物。

    Abstract:

    Wegscheiderite is a.n anhydrous alkali carbonate mineral which was first found in Green River basin of Wyoming, U. S. A. as a new mineral, and in China was first found at Biyang basin, Henan province, in 1982. The chemical composition of this mineral is sodium carbonate and sodium bicaxbanate, and the chemical formula is Na2C03.3NaHCO3. The crystal is plate-shaped, color- less, and transparent, occurring mainly in alkali ore stratum composed of nah- colite. Different methods of identification have been performed on the minera lsamples.It is determined as follows: The mineral is biaxial(-),and the indi- ces of refraction are:Ng =1 .531, Nm=1.524, Np=1.435; 2V=31.45º (talc.); Cell parameters: a=10.046, b=15.633, c=3.492,。a=92º8', β=95º42', γ= 108º34'. The strongest lines in the powder diffraction pattern are; 3.70 (35), 2 .97 (100),2.67 (41),2.213 (60).The principal infrared absorption bonds are;2616, 1692, 1662, 1359, 1048, 1018, 839, and 677cm-1. From the characteristics of occurrence and association, wegscheiderite is formed in continental carbonate lake which is rich in sodium and higher in pco2,under h馆hex temperature and fast evaporation.

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杨清堂,1987,我国首次发现的碳氢钠石[J].岩石矿物学杂志,6(1):87~91. Yang Qingtang,1987,[J]. Acta Petrologica et Mineralogica,6(1):87~91.

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