苏北东海花岗质岩石中主要造岩矿物和副矿物的地球化学特征
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Geochemical Characteristics of the Major Rock-forming Minerals and Accessory Minerals from the Granitoids of Donghai Area, Northern Jiangsu
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    摘要:

    苏北东海地区主侵入花岗岩类岩石属Ⅰ型花岗岩类。其主要造岩矿物为阳起角闪石、富镁黑云母、更长石、钾长石和石英。主要副矿物为榍石、磷灰石、锆石、磁铁矿等。主侵入岩体的形成温度为910—690℃,logfo2=-12,fH2O=(1.3—1.8)×108Pa,log(fH2O/f(HF))=3—4。第一类过渡元素富集于角闪石、黑云母和榍石中,而在更长石、钾长石和石英中明显亏损。由于榍石、角闪石、黑云母和更长石对全岩REE含量的贡献最大,因此它们控制了本区花岗岩类岩石的稀土配分模式。前三者富重稀土,负Eu异常较强,斜长石相对富轻稀土,并表现为正Eu 异常。因此可以认为随着花岗质岩浆中铁镁矿物和斜长石的分离,将会导致残余岩浆中第一类过渡元素、重稀土元素和Eu的亏损。

    Abstract:

    The quartz monzonite-monzonitic granite masses are the main intrusive pro- ducts in Donghai area, northern Jiangsu and can be classified as I-type grani- toids, The major rock-forming minerals are composed of actinolitic hornblende, Mg-rich biotite, oligoclase, perthite and quartz, with sphene, apatite, zircon, mag- petite etc, as chief accessories. The thermodynamic calculation indicates that the physicochemical crystallization conditions of the magma are t=910一690℃, log fo2=-12, f H2o=(1.3-1.8) × 108Pa and log(fH2o/fHF)=3一4 , The 1 st set of transition elements are abundant in hornblende, biotite and sphene, but are obvi- ously reduced in oligoclase, perthite and quartz, As hornblende, biotite and oligo- clase play the most important part in the contribution of REE contents to the whole rocks, they control the REE distribution patterns of the rocks, These three minerals are usually rich in HREE with comparatively large negative Eu ano- maly, while plagioclase is relatively rich in LREE and exhibits positive Eu ano- maly, Thus, with the advance of magmatic fractionation, the mafic minerals and plagioclase will be gradually separated from each other, anal this will lead to the depletion of HREE, transition elements of 1st set and Eu contents.

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汪建明,李康强,杨年强,丁桂春,1989,苏北东海花岗质岩石中主要造岩矿物和副矿物的地球化学特征[J].岩石矿物学杂志,8(2):163~172. Wang Jianming Li Kangqiang Yang Nianqiang Ding Guichun,1989,Geochemical Characteristics of the Major Rock-forming Minerals and Accessory Minerals from the Granitoids of Donghai Area, Northern Jiangsu[J]. Acta Petrologica et Mineralogica,8(2):163~172.

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