北岭金矿中的针碲银金矿的研究
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国家自然科学基金和地质行业基金联合资助(49372131


A Study of Sylvanite from the Beiling Gold Deposit, Henan Province
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    摘要:

    针碲银金矿产于北岭金矿的晚期矿化阶段,赋存于梳状排列网脉状的石英中,与自然金伴生。矿物组合为针碲银金矿-自然碲-碲铅矿-自然金-石英和针碲银金矿-碲镍矿-碲铅矿-石英。自然碲、碲镍矿、碲铅矿在针碲银金矿中呈包裹体产出。针碲银金矿呈柱状、板状、粒状晶形,聚片双晶,具强非均质性及双反射和反射多色性,Hv50=216—219 kg/mm2。其化学成分: Ag10. 58%—12. 36%, Au 23. 70%—24. 51%, Te 61. 67%—62. 30%,含少量As、Cu、Zn、Fe和Ni,分子式为AgAu1.0494—1.2691Te4.215—4.9182。X射线衍射的强线有: 3. 054 (85), 2. 153(31), 1. 984 (18),晶胞参数:a0=8. 9502°A,b0=4. 4973°A,c0=14. 7063°A,β=145°58′。在成矿溶液中Au和Te呈络合物运移,在温度低、硫逸度低、偏酸性及大气水参与的条件下,发生金的富集成矿作用。针碲银金矿及其它碲化物是北岭金矿晚期矿化阶段的特征标志,对寻找大型火山岩浅成热液碲化物型金矿具有重要的意义。

    Abstract:

    Sylvanite was formed at the late mineralization stage of the Beiling gold deposit and occurs in comby network quartz, associated with native gold. The mineral assemblage includes sylvanite-na tive tellurium-altaite-native gold-quartz and sylvanite-melonite-altaite-quartz. Native tellurium,melonite and altaite exist as inclusions in sylvanite. Sylvanite occurs in columnar, tabular and grained forms and assume polysynthetic twin with strong anisotropy and bireflectance.Hv50=216—219 kg/mm2. Chemical composition:Ag 10.58%—12.36%,Au 23.70%—24.51%, Te 61.67%—62.30%, with small amounts of As,Cu, Zn, Fe and Ni. Chemical formula is Ag Au1.0494—1.2691Te4.215—4.9182. The strongest X-ray diffraction lines are 3.054(85),2.153(31),and 1.984(18). Unit cell parameters:a0=8.9502°A,b0=4.4973°A,c0=14.7063°A andβ=145°58′. The ore deposit was formed at 115.2—161.8℃and lower sulfur fugacity. Hydrogen and oxygen isotopic studies show that ore-forming fluids came from meteoric water of low salinity.The gold deposit is considered to be of volcanic epithermal type.

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赵嘉农,任富根,李增慧,丁士应,1997,北岭金矿中的针碲银金矿的研究[J].岩石矿物学杂志,16(1):75~80. Zhao Jianong, Ren Fugen, Li Zenghui, Ding Shiying,1997,A Study of Sylvanite from the Beiling Gold Deposit, Henan Province[J]. Acta Petrologica et Mineralogica,16(1):75~80.

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