镍钛改性膨润土对铬的吸附性能研究
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P578.967 O647.3

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辽宁省教育厅科学研究计划资助项目(A类)项目(2004D080)


The adsorption properties of Ni-Ti modifierd montmorillonite for Cr(VI)
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    摘要:

    以钠基膨润土为原料,制备镍钛交联改性膨润土、镍钛有机复合改性膨润土,并应用于含铬模拟废水的处理。探讨了改性膨润土的用量、pH值、吸附时间等最佳使用条件,比较了原土、交联改性土、有机复合改性土对铬的吸附效果。结果表明改性土的吸附效果明显优于原土,在最佳实验条件下,交联改性土、有机复合改性土对Cr(Ⅵ)的去除率分别达到了87%和96%。两种改性土对铬吸附行为均符合Langmuir吸附等温方程,饱和吸附量和Lang-muir常数分别为3.1827mg/g、8.5543mg/g和3.5007、1.2738。

    Abstract:

    Two kinds of modified montmorillonites were synthesized from Na-montmorillonite, namely Ni-Ti-cross-linked-montmorillonite and Ni-Ti-organic compound montmorillonite. Some factors were examined in the experiments of Cr(Ⅵ)=bearing wastewater disposal. The feeding amount of modified montmorillonite, the pH of wastewater and the stirring time, and the Cr(Ⅵ)removal rate on three kinds of montmorillonites were studied. The results show that the removal rate of Cr(Ⅵ) on modified montmorillonite under optimized conditions has reached 87% and 96%, that the adsorption obeys Langmuir adsorption isotherm, and that the saturated adsorption amount and the Langmuir constant are 3.182?7 mg/g,8.554 3 mg/g and 3.500 7, 1.273 8, respectively.

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孙伶 邵红 王恩德,2005,镍钛改性膨润土对铬的吸附性能研究[J].岩石矿物学杂志,24(6):543~546. SUN Ling, SHA Hong, WANG En-de,2005,The adsorption properties of Ni-Ti modifierd montmorillonite for Cr(VI)[J]. Acta Petrologica et Mineralogica,24(6):543~546.

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  • 收稿日期:2004-12-19
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