The FeCl3 graphite intercalation compounds (FeCl3-GICs) have aroused special attention for their highly electrical conductivity and stability. In this paper, FeCl3-exfoliated graphite intercalation compounds (Abs. FeCl3-EGICs) have been synthesized under the protection of nitrogen gas with the melting salt method. The experimental results show that pure stage-I FeCl3-EGICs can be synthesized at 360℃ for 12 hours, and pure stage-II FeCls3-EGICsat 460℃ for 12 hours when FeCl3 is excessive. In addition, the electrical conductivity of FeCl3-EGICs was measured at different temperatures, the number of stage Ⅰ EGICs is 7.513×10 6S·m-1 at 297K which is 3.7 times larger than pristine exfoliated graphite, and stage Ⅱ is 6.87×10 6 S.m-1at the same temperature which is 3.4 times larger. The conductance of FeCl3-EGICs is similar to that of metals, and its electrical resistivity shows a linear relation with the temperature from 297K to decomposition temperature. The resistivityincreases with temperature, with the mechanism being phonon scattering.