一种新发现软玉的宝石学特征研究
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国家自然科学基金(40873021); 广东省自然科学基金(8151027501000015)


A study of gemological characteristics of a new nephrite jade material
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    摘要:

    根据常规宝石常数的测定,X射线衍射、扫描电镜、电子探针及激光烧蚀等离子发射光谱与质谱仪(LA-ICPMS)等仪器的测试,首次报道了中国贵州一个新发现软玉玉料的宝石学特征。该玉料颜色以瓷白色-灰白色为主,比常见软玉的透明度稍低,矿物结构以细长叶片状交错结构和纤维变斑交织结构为主,摩氏硬度约为5.8,折射率1.600~1.608,相对密度2.88,抗压强度为357.40~446.75 MPa,稍低于软玉的标准数据。分析结果显示,其矿物成分以透闪石为主,含有透辉石、方解石、钠长石(?)和石英矿物包体,透闪石的晶体化学式为(Cr0.02Al0.03Fe0.03Mg4.94)(Na0.02K0.01Ca1.98)(Si4.25O11)2(OH)2,主量元素富硅,不含钛,玉料稀土元素含量较高,轻重稀土元素分异明显,LaN/YbN为30~60,重稀土元素亏损,具Eu、Ce负异常,稀土元素配分模式为较陡的右倾斜型,和国内目前已经发现的其他产地软玉相比具有独特性,是一种新的软玉质材料。

    Abstract:

    The research on the origin and locality of jade is one of the most important items in the study of gemology and jade archaeology, and a basic method for study is to comprehend the detailed characteristics of jades from different producing localities. Based on the conventional gem constants and the analysis using such means as X-ray diffraction, scanning electron microscopy, electron microprobe analysis, and laser ablation plasma mass spectrometer (LA-ICPMS), this paper reports for the first time the gemological characteristics of a new nephrite material from a new locality of Guizhou Province in China. With mainly the porcelain white-gray color and micro-leaf-like crisscross and microporphyroblastic fiber-crossed structures, The transparency of this material is a little lower than that of common nephrites. The other data, such as the Mohs hardness scale of about 5.8, the refractive indexes of 1.600~1.608, the S.G of 2.88 and the compressive strength of 357.4~446.75 MPa, are slightly below the standard data of nephrite. The results show that the mineral components of the new nephrite type are mainly tremolite, with subordinate diopside, calcite, albite (?) and quartz mineral inclusions. The crystal chemical formula of tremolite is (Cr0.02Al0.03 Fe0.03 Mg4.94)(Cr0.02 Na0.023 K0.01Ca1.98) (Si4.246 O11)2 (OH)2. As for major elements, silicon is rich, but there exists no titanium. The content of rare earth elements is high, with obvious HREE and LREE differentiation. LaN/YbN ratios vary from 30 to 60. There exists depletion of HREE, with negative Eu, Ce anomalies. The REE distribution pattern is of relatively steep rightly-oblique type. In comparison with the nephrites found in other areas, the authors hold that the nephrite material studied in this paper is unique and seems to be a new nephrite jade material.

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李榴芬,丘志力,梁婷,赵丽苹,江启云,陈瑶,2011,一种新发现软玉的宝石学特征研究[J].岩石矿物学杂志,30(Z1):63~72. LI Liu-fen, QIU Zhi-li, LIANG Ting, ZHAO Li-ping, JIANG Qi-yun, CHEN Yao,2011,A study of gemological characteristics of a new nephrite jade material[J]. Acta Petrologica et Mineralogica,30(Z1):63~72.

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  • 收稿日期:2011-05-20
  • 最后修改日期:2011-07-07
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