凉山瓦西乡南红玉中的赤铁矿包裹体特征与成因
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国家自然科学基金资助项目(41172054, 40572026)


The features and genesis of hematite in Nanhong jade from Waxi Township, Liangshan
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    摘要:

    瓦西乡产出的南红玉中的红色点状及火焰纹典型包裹体分别是石英中的红色球粒与红色管状包裹体。鏡下及扫描电镜(SEM)研究,红色球粒分布在"三色"层水晶的菱面体单形晶面的间歇层面中,由红色核、黑色壳和红色表层组成;火焰纹管状包裹体主要出现在条带水晶中,管的方向垂直水晶的菱面体晶面,管的内壁呈黑色,外壳为红色。其球粒表层或管外壳的颜色、厚度及透光性则直接影响南红的颜色质量与润泽性。研究表明,球粒状和火焰状包裹体主要由片状、鳞片状或板片状赤铁矿组成;球粒圈层中的赤铁矿晶体c轴取向呈规律变化,可能与其V2O5含量有关。据水晶晶体中的球粒、管及共生矿物绿帘石、黄铜矿包裹体的红外光谱(IR)及流体包裹体均一法测温与激光拉曼(LRS)分析,球或管的赤铁矿属含有机质的低温热液(约160℃)成因,成矿溶液中的有机质也是促使铁氧化物凝聚形成具不同圈层结构的红色球粒与管的主要原因。有机质可能来自下二叠统茅口组碳酸盐。

    Abstract:

    The red dot and flame figure inclusions in Nanhong jade are red spherulite and red tube-like inclusions in quartz. Microscope observations and scanning electron microscope studies show that the red spherulites include the red core, black coccosphere and red surface, and are distributed in the intermittent layers of rhomb in "three-color" type quartz. The flamed tube-like inclusions mainly occur in striped quartz, perpendicular to the rhomb of quartz. The interior of the tube is black with red shell. The color and transparency of the spherulite and red tube-like inclusions have directly effects on the color and luster quality of Nanhong jade. Studies show that the red spherulite and red tube-like inclusions are mainly composed of platy hematite. The directions of c-axis in hematite from spherulites change regularly, which is likely related to its V2O5. The relationships between quartz and associated minerals and their analytical results indicate that hematite is of hydrothermal origin, and its temperature is about 160℃. The organic matter of the fluids, which led to the formation of spherulite and red tube-like hematite inclusions, probably came from the carbonate in Permian Maokou Formation.

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张良钜,宋楚欣,阮青锋,曾伟来,李东升,曾南石,胡惠驿,覃敏锋,2015,凉山瓦西乡南红玉中的赤铁矿包裹体特征与成因[J].岩石矿物学杂志,34(2):237~245. ZHANG Liang-ju, SONG Chu-xin, RUAN Qing-feng, ZENG Wei-lai, LI Dong-sheng, ZENG Nan-shi, HU Hui-yi, QIN Min-feng,2015,The features and genesis of hematite in Nanhong jade from Waxi Township, Liangshan[J]. Acta Petrologica et Mineralogica,34(2):237~245.

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  • 收稿日期:2014-12-19
  • 最后修改日期:2015-01-28
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  • 在线发布日期: 2015-04-01
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