福建龙岩风化型高岭土矿床中粘土矿物的研究
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A Study of Clay Minerals from the Longyan Weathering-Type Kaolin Deposit, Fujian Province
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    摘要:

    福建龙岩高岭土矿床风化剖面各风化带有特征的粘士矿物组合。高岭矿物在风化剖面中由下而上逐渐增多,反映出花岗岩中原生矿物高岭土化程度逐渐加强的阶段性变化。高岭石结晶较差,以薄片状或具长石、云母假象的大于2um粒级出现。埃洛石为7或10型,多富集在小于2um粒级中。埃洛石结晶形态的多样性及多变性与矿物形成时的物质来源及水化状态有关。长石蚀变为高岭矿物,可以经由水铝英石向球状或管状埃洛石直到高岭石的转变、长石的固态转变和从溶液中直接结晶等几个途径。白云母的高岭土化能直接转变为具云母假象的高岭石。

    Abstract:

    Detailed studies have been made on composition and characteristics of clay minerals as well as kaolinization process of feldspar in the Longyan weathe- ring type kaolin deposit of Fujian province by means of X-ray diffraction, infrared absorption spectrometry, analytical electron microscopy, scanning electron microscopy and chemical analysis. The results suggest that the weathering profile of the granite shows distinct vertical zonality and can be divided in downward succession into three zones, i. e.,strongly weathering, weakly weathering and parent rock zones, which make up a typical weathering crust formed by in-situ weathering of the parent rock. The clay minerals in the kaolin deposit are rather simple and consist mainly of kaolin minerals (kaolinite as well as 7A and/or 10A halloysite) and hydromuscovite. Each weathering zone has its own characteristic clay mineral assemblage: the strongly weathering zone and the weakly weathering zone are noted respectively for kaolin mineral-hydromuscovite assemblage and hydromuscovite-kaolin mineral assemblage. The difference in clay mineral composition indicates kaolinization degrees of feldspar at different stages. Studies show that kaolinite in the Longyan kaolin deposit is poorly crystallized and generally assumes irregular flaky form. Book-shaped kaolinite after pseudo- morph of feldspar and large flaky crystals after pseudomorph of mica can also be recognized with grain size generally larger than 2}m. Halloysite is of 7A and/or 10A type and is mostly less than 2μm in granularity;it is characterized by diversity in shape with the tubular form being most common. The apparent unrolling and longitudinal fracturing displayed by many tubules are related to dehydration of halloysite. The conversion of feldspar into kaolin minerals results from the following process: First there is a continuous transformation Series from subspaerical amorphous allophane through spherical or tubular halloysite to hexagonal flaky kaolinite; second,some feldspar is directly altered into kaolin minerals either by solid-state transformation or by crystallization from solutions that have filled etch pits in feldspar. The muscovite-kaolinite transition may take place directly. forming kaolinite after pseudomorph of biotite.

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张天乐,王宗泉,1990,福建龙岩风化型高岭土矿床中粘土矿物的研究[J].岩石矿物学杂志,9(3):234~244. Zhang Tianle, Wang Zongliang,1990,A Study of Clay Minerals from the Longyan Weathering-Type Kaolin Deposit, Fujian Province[J]. Acta Petrologica et Mineralogica,9(3):234~244.

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