山西省河曲县铺沟铝土矿中勃姆石的矿物学特征及其成因探讨
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Mineralogical Characteristics of Boehmite from the Pugou Bauxite Deposit in Hequ County, Shanxi Province
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    摘要:

    本文对山西省河曲县铺沟铝土矿中的勃姆石进行了偏光显微镜、X射线粉末衍射、红外光谱、扫描电镜鉴定,研究了其矿物学特征。勃姆石晶体形态呈菱形、柳叶状及鳞片状。X射线衍射特征峰有:d020=6.109A,d120=3.160A,d=051=1.863A,d200=1.848A,d220=1.769A,d080=1.529A;晶胞参数为a0=3.690A,b0=12.162A,c0=2.866A;红外光谱反映的特征谱带是3300cm-1和3078cm-1。文章还对其成因进行了探讨,认为主要是由胶体晶化及高岭石脱硅转变而来。

    Abstract:

    Pugou bauxite is a small-sized ore deposit, in which boehmite was discovered for the first time. With the help of polarizing microscope, XRD, 1R and SEM, the author has made a detailed study on the mineralogical properties of boeh mite. Boehmite, γ-A100H, belongs to orthorhombic system. α=β=γ=90º,a0=3.690A, bo=12.162A,co=2. 866A.The crystals are mainly blades and rhombohedral in shape, colorless or yellowish in color,and 0.5μ to 4μ in size. The XRD analyses demonstrate that the charaos}eistic lines of boehmite are d020=1.848, d22o=1.769 and do8o=1.529, The IR analyses show that the characteristic frequency bands are 3300cm-l, 3078em-1, 793cin-1and 364cm-1. Based on indoor studies and field investigation, the author puts forward a preliminary opinion concerning the origin of boeh mite. It is considered that boehmite was formed mainly in two ways during the supergene process: mainly through the direct crystallization of the Si-Al gel and secondarily from the desi- lication of kaolinite.

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邓红灯,1991,山西省河曲县铺沟铝土矿中勃姆石的矿物学特征及其成因探讨[J].岩石矿物学杂志,10(1):63~67. Deng Hongdeng,1991,Mineralogical Characteristics of Boehmite from the Pugou Bauxite Deposit in Hequ County, Shanxi Province[J]. Acta Petrologica et Mineralogica,10(1):63~67.

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