湖北天然绿松石与优化处理绿松石的宝石学鉴别特征
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国家自然科学基金重点项目(41530319);国家标准技术委员会研制项目(20140710-T-334);中国地质大学(武汉)珠宝检测技术创新中心资助项目(CIGTWZ-2018015)


Gemological identification of natural turquoise and treatment turquoise in Hubei
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    摘要:

    本文主要以湖北天然绿松石、浸胶绿松石和注有色胶绿松石为研究对象,结合优化处理工艺过程及所用的胶水混合液,通过宝石学常规测试以及扫描电子显微镜、红外光谱仪、激光拉曼光谱仪和紫外可见光谱仪等宝石学现代仪器的测试分析,研究有效鉴别湖北天然绿松石和浸胶绿松石、注有色胶绿松石的测试方法。结果表明,注有色胶绿松石的颜色较呆板,浸胶和注有色胶绿松石相对密度较低且在长波紫外荧光灯下显示强至弱的蓝色荧光;扫描电镜下可见浸胶和注有色胶绿松石微晶之间的空隙被不同程度的胶质物充填,但该方法为有损法,不推荐使用;红外光谱中2 930、2 860、1 730、1 460 cm-1附近由有机物基团振动所致的红外吸收谱带可有效区分三者,是最为快速、无损、准确的方法;拉曼光谱中2 942、2 873、1 452、1 620、830 cm-1附近的吸收峰可作为鉴别湖北天然绿松石和浸胶或注有色胶绿松石的重要依据;紫外可见光谱中较弱的429 nm吸收峰和宽缓的677 nm吸收带可作为区分天然绿松石和注有色胶绿松石的鉴别依据,但无法区分天然绿松石和浸胶绿松石。

    Abstract:

    Using conventional gemological methods, SEM, FTIR spectrum, Raman spectrum and UV-VIS spectrum analysis, combined with the processes of treatment and the mixture of glue, the authors found out the best way to distinguish the dipped turquoise, injected turquoise and the natural ones. The color of injected turquoise is stiff, while the color of dipped turquoise and injected turquoise under the long-wave UV fluorescent lamp is pale to strong blue. The authors found glue in dipped turquoise and injected turquoise under SEM, which could help differentiate three kinds of turquoise; however, this method is ruinous. The result shows that FTIR spectrum can differentiate Hubei turquoise from dipped turquoise and pigmented turquoise with 2 930, 2 860, 1 730, 1 460 cm-1 absorption bands caused by the vibration of organic groups; this is the fastest, accurate and non-destructive testing method; meanwhile, 2 942, 2 873, 1 452, 1 620, 830 cm-1 absorption peaks in Raman spectra are beneficial to distinguish the dipped turquoise and pigmented turquoise with the natural ones; UV-VIS spectra of the weaker 429 nm absorp-tion peak and the 677 nm absorption band can be used as the identification basis to distinguish the natural turquoise and pigmented turquoise, but they are unable to distinguish between natural turquoise and dipped turquoise.

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徐娅芬,狄敬如,2018,湖北天然绿松石与优化处理绿松石的宝石学鉴别特征[J].岩石矿物学杂志,37(4):646~654. XU Ya-fen, DI Jing-ru,2018,Gemological identification of natural turquoise and treatment turquoise in Hubei[J]. Acta Petrologica et Mineralogica,37(4):646~654.

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  • 收稿日期:2017-11-08
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  • 在线发布日期: 2018-07-10
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