海泡石持久脱除空气中微量甲醛的方法与机理
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1.韶关学院;2.湖南科技大学

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P579, X511

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国家自然科学基金项目(面上项目,重点项目,重大项目)


Methods and mechanisms for lastingly removing traces of HCHO in air by sepiolite
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Hunan University of Science and Technology

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    摘要:

    为克服海泡石吸附甲醛达到饱和后失去吸附功能的缺陷,利用静态吸附实验研究热处理温度对海泡石吸附微量甲醛能力的影响,并运用扫描电镜、X射线衍射、红外吸收光谱、热重和BET比表面检测等方法研究相关机理。结果表明,硅胶干燥剂的存在明显提高海泡石对空气中微量甲醛的吸附能力,并能降低甲醛含量至法定安全上限以下,在≦400 ℃的温度热处理后海泡石仍能保持良好的甲醛吸附性能,但经≧500 ℃热处理后甲醛吸附性能显著降低。结合表征研究,认为海泡石相的结晶水对甲醛形成化学吸附,而其以沸石孔洞为主的结构微孔有利于物理吸附的甲醛占位,≧450 ℃的热处理使结晶水不可逆脱出,沸石孔坍塌,从而吸附性能显著降低。该研究表明海泡石的吸附性能可以在低于450 ℃的温度热再生,脱出的甲醛也可以通过燃烧消除。通过间歇性热再生可使海泡石持续脱除空气中的微量甲醛。

    Abstract:

    In order to overcome the shortage of adsorption ability loss after sepiolite is HCHO-saturated, static adsorption experiments were applied to evaluate the effects of heating temperature on absorbing traces of gaseous HCHO for sepiolite, and scanning electronic microscopy, X-ray diffraction, infrared absorption spectroscopy, thermogravimetry and BET specific surface area analysis were adopted to investigate the related mechanisms. It was resulted that silica-gel desiccant elevated the sepiolite’s adsorption ability of traces of gaseous HCHO and reduced the final HCHO concentration lower than the legal safety upper limit. The sepiolite heated at temperature ≦400 ℃ held favorable HCHO absorption properties, while those heated at temperature ≧500 ℃ showed significantly reduced HCHO absorption properties. Under comprehensive characteristics, it is proposed that the crystalliferous water in sepiolite could chemically absorb HCHO and the structural microholes, basically composed of zeolite holes, could be occupied by HCHO through physical absorption. After heated at temperature ≧450 ℃, sepiolite lose the crystalliferous water irreversibly and the zeolite holes collapse that lead to the adsorption ability drastically reducing. The research supports sepiolite to regenerate adsorption ability by heating at temperature below 450 ℃ at which the escaped HCHO could be eliminated by burning,so sepiolite could enduringly remove traces of HCHO in the air by intermittently thermal regeneration.

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  • 收稿日期:2021-08-22
  • 最后修改日期:2022-07-16
  • 录用日期:2022-07-21
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