地球早期碳循环与大氧化事件(沈其韩院士百年华诞论文专辑)
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中国地质科学院 地质研究所 自然资源部深地动力学重点实验室

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国家自然科学基金资助项目(42002060);自然资源部深地动力学重点实验室自主研究课题(J1901-23)。


Carbon cycle in the early Earth and the great oxidation event
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Key Laboratory of Deep-Earth Dynamics of Ministry of Natural Resources,Institute of Geology,Chinese Academy of Geological Science

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    摘要:

    碳是影响地球宜居性的重要元素,地表系统和地球深部之间的碳循环作用对于全球气候的变化具有非常重要的影响。现今地球主要通过俯冲作用和火山作用调节着全球碳循环过程。然而,地球早期碳循环过程和现今地球存在显著的差异。本文结合前人的相关研究成果,综合探讨了地球原始碳的来源、地球早期碳循环过程及大氧化事件的成因等问题。地球是从太阳星云中通过星子吸积增生演化形成的,地球上的碳有一部分来自于地球的初始组成物质,还有一部分是通过大碰撞事件以及后期增生过程获得的。在地球形成之初的岩浆海时期,地核和地幔之间的分异作用会使地核富集碳而地幔极度亏损碳;岩浆海和地球早期大气之间的相互作用可以把大气中的碳带入地幔中。当原始地球和具有高C/N及C/S比值的星胚碰撞时,可以提高地球的碳含量;此外,富集挥发份的球粒陨石后期增生作用也可以为地球带来额外的碳。在早期板块构造阶段,板块俯冲的地热梯度要比现在高100摄氏度左右,俯冲的蚀变洋壳和洋底沉积物在很浅部就会通过脱碳反应或者熔融作用发生完全的脱碳作用,只有少量的碳可以通过碳酸盐化橄榄岩带入地球深部,由此造成的温室效应可以抵消早期太阳光度不足对地表气候的影响。地球早期碳循环作用和大氧化事件具有紧密的联系,大气中CO2含量的升高,有机物的埋藏,无机碳酸盐和有机碳俯冲循环效率的差异等都是形成大氧化事件的关键因素。

    Abstract:

    Carbon is an important element affecting the habitability of the Earth. The carbon cycle between the Earth’s surface and its deep interior has a very important impact on global climate change. Nowadays, the Earth regulates the global carbon cycle mainly through subduction and volcanism. However, the process of carbon cycle in the early Earth is significantly different from that in the present Earth. Based on the previous research results, this paper comprehensively discusses the source of the Earth"s original carbon, the process of the Earth"s early carbon cycle and the causes of the great oxidation event (GOE). The Earth was evolved from the solar nebula through the accretion of planetesimals. Part of the carbon on the Earth comes from the initial composition of the Earth, and part is obtained through giant impacts and late veneer. During the early Earth magma ocean process, the differentiation between the Earth"s core and mantle will lead to the enrichment of carbon in the Earth"s core and the loss of carbon in the mantle; the interaction between the magma ocean and the Earth"s early atmosphere can bring the carbon from the atmosphere into the mantle. When the proto-Earth collides with a planetary embryo that has high C / N and C / S ratios could give rise to the carbon inventory in the Earth. In addition, the late veneer of chondrites enriched in volatiles can also bring additional carbon to the Earth. In the early stage of plate tectonics, the P-T trajectory of ancient subduction is hotter than the modern subduction zone by 100℃. The subducted altered oceanic crust and ocean floor sediments would undergo complete decarbonation and carbonate melting at shallow depth, and only a small amount of carbon can be brought into the deep mantle by carbonated peridotite. The resulting greenhouse effect can get around the faint young Sun paradox. The early carbon cycle of the Earth is closely related to the great oxidation event. The increase of CO2 content in the atmosphere, the burial of organic matter, and the difference of subduction efficiency between inorganic carbonate and organic carbon are the key factors for the formation of the great oxidation event.

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  • 收稿日期:2021-10-11
  • 最后修改日期:2022-01-19
  • 录用日期:2022-03-21
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