白云鄂博西矿区伴生型萤石矿床的稀土元素地球化学特征及其指示意义
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中国地质科学院

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中央型公益性科研院所基本科研业务费专项(批准号KK2005),地质调查局地质矿产调查评价专项项目(Nos. DD20190816,DD20190606),国家自然“异常富集稀土碳酸岩成因及其对稀土元素超常分异-富集控制机理研究”(No.42072114),科技成果转化项目(编号HE2122、HEHE2133)联合资助。 ,2),王春连2),刘殿鹤2,4),王军2),柯昌辉2),游超3),


REE geochemical characteristics of associated fluorite deposit in the west mine of Bayan Obo and their implications
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Chinese Academy of Geological Sciences

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    摘要:

    白云鄂博伴生型萤石矿床是举世瞩目的超大型矿床,但矿床成因目前仍然存在争议。本文在系统研究了白云鄂博西矿区地质特征及含萤石矿石的分布规律的基础上,针对萤石矿石与赋矿H8白云岩开展了微量、稀土元素地球化学研究。研究结果表明:西矿区萤石矿石属于白云石型矿石,萤石和白云岩的稀土元素特征均为轻稀土相对富集,重稀土相对亏损,萤石和白云岩稀土配分曲线具有相似同步性。所有样品均表现出Ba、Th、Sm、Ce的含量相对较高,特别是Ba,Th的含量明显偏高,矿区萤石单矿物δEu值为0.93~1.14,既有正异常又有负异常,δCe的值为1.15~2.11,平均为1.51,表现为Ce的正异常。综合研究区萤石矿地质、微量、稀土元素特征和(Y+La)-Y/La、La/Ho-Y/Ho、Tb/Ca-Tb/La关系图,结合前人对萤石流体包裹体的研究结果,认为白云鄂博西矿区伴生型萤石矿属于中-高温热液交代型萤石矿床。与我国典型沉积改造型、热液填充型萤石矿床不同,矿床成因与侵入花岗岩无关,主要成矿物质F和Ca元素源自加里东期钙质碳酸岩岩浆衍生的中-高温流体对早期富镁铁碳酸岩的交代作用。

    Abstract:

    The Bayan Obo associated fluorite deposit is a super-large deposit attracting worldwide attention, but the genesis of the deposit is still controversial. Based on the systematic study of the geological characteristics and the distribution of fluorite-bearing ores in the western Bayan Obo mine, the geochemical study of trace and rare earth elements of fluorite deposit and ore-bearing H8 dolomite is carried out in this paper. The results show that the fluorite deposit in the western mining area belongs to the dolomite-type ore. The REE characteristics of both fluorite and dolomite are relatively enriched in LREE and relatively depleted in HREE. The REE distribution patterns of fluorite and dolomite have similar synchronization. The contents of Ba, Th, Sm and Ce in all samples are relatively high, especially the contents of Ba and Th are obviously high. The δEu values of fluorite ores in the mining area range from 0.93 to 1.14, with both positive and negative anomalies. The δCe values range from 1.15 to 2.11, with an average of 1.51, showing positive anomalies of Ce.Based on the geological characteristics of fluorite deposit, trace and rare earth elements and plots of (Y+La)-Y/La, La/Ho-Y/Ho and Tb/Ca-Tb/La, combined with previous studies on fluid inclusions in fluorite, it is concluded that the associated fluorite deposit in the western Bayan Obo mine belongs to medium-high temperature, hydrothermal metasomatism type fluorite deposit. Different from typical sedimentary-reworked and hydrothermal filling fluorite deposits in China, the genesis of the deposit has nothing to do with intrusive granite, and the main ore-forming materials of F and Ca elements are derived from the metasomatism of early mafic carbonate rocks by medium-high temperature fluids derived from caledonian calcareous carbonate rocks.

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  • 收稿日期:2021-12-23
  • 最后修改日期:2022-07-14
  • 录用日期:2022-07-21
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