The Southern Da Hinggan Mountains is one of the most important metallogenic belt, where varied types of mineral deposits have been reported over the past few decades. The Hongling(Haobugao) Pb-Zn polymetallic ore deposit is situated in the northeast of Huanggang-Ganzhuermiao polymetallic metallogenic belt, which is located in the southern segment of the Da Hinggan Mountains, Inner Mongolia. The ore genesis and ore controls of the deposit has been widely reported, but the detailed geological work, especially the lithology of the wall rock, and the spatial distribution of mineralization and alteration in the mining area is still weak. Based on the field observation, petrographic and SEM/EDS results of the ore and altered wall rocks, this paper proposed that the Permian of the area comprise of marble and meta-volcanic or volcaniclastic rocks which has been referred to as meta-sedimentary clastic rocks. The discovery of pressure shadow with chalcopyrite and sphalerite aggregate as the core mineral imply a primary copper and zinc mineralization of Permian. Except the dominant skarn mineralization, we also confirmed some other mineralization types in the mining area, including breccia type, hydrothermal veins and carbonate replacement type. Varied types of mineralization provide new idea for the ore prospecting in the area.