河北宽城蛇纹石玉的宝石矿物学特征研究
DOI:
CSTR:
作者:
作者单位:

1.河北地质大学地球科学学院;2.河北地质大学宝石与材料学院

作者简介:

通讯作者:

中图分类号:

P574.2;P575.4

基金项目:

国家自然科学基金(Z20210005),河北省岩石矿物材料绿色开发重点实验室(筹)项目资助。


Gemological and Mineralogical Characteristics of Serpentine jade from Kuancheng county, Hebei Province, China
Author:
Affiliation:

Hebei GEO University

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    河北宽城蛇纹石玉主要产于河北省承德市宽城满族自治县与辽宁省凌源市交界处,玉石结构细腻,颜色可呈肉红色、绿色,当地市场称之为“热河玉”。本文通过常规宝石学测试结合激光拉曼光谱、电子探针、X射线粉晶衍射、激光剥蚀等离子质谱以及可见光吸收光谱等手段对其进行系统测试,并采用伽玛能谱仪对其放射安全性进行检测。结果表明:肉红色样品折射率及相对密度值均较低,折射率约1.54-1.55,相对密度约2.33-2.43,绿色样品折射率约1.55-1.56,相对密度约2.58-2.62;肉红色样品的主要组成矿物为斜纤蛇纹石,主要呈纤维交织结构、纤维柱粒交织结构,局部可见变余生物骨架结构,次要矿物有方解石和透辉石;绿色样品的主要组成矿物为叶蛇纹石,呈更加细腻的纤维交织结构,次要矿物为滑石及四方硫铁矿;元素分析显示肉红色样品中Fe和Mn元素含量相对较高,Fe元素含量范围在184.9×10-6~951.7×10-6,Mn元素含量为106.4×10-6~287.3×10-6,绿色样品中Fe元素含量极高,可达5979×10-6~6359×10-6,结合可见光吸收光谱测试认为Fe3+、Fe2+以及Mn3+综合作用是导致样品呈现肉红色的主要原因,而Fe2+和Fe3+则是导致绿色的主要原因;放射性检测结果显示样品的内、外照射指数及放射性比活度值均低于标准要求,对人体无放射性危害。

    Abstract:

    Serpentine jade in Kuancheng county, Hebei Province is mainly founded at the junction of the eastern edge of Kuancheng Manchu Autonomous County, Chengde City, Hebei Province and Lingyuan City, Liaoning Province. This kind of jade is exquisite in structure, and the color can be flesh red or green, which is called "Rehe jade" in the local market. In this paper, serpentine jade samples with flesh red and green color from Kuancheng county were systematically investigated using the conventional gemological methods combined with Laser Raman Spectroscopy, electron probe microanalyzer (EPMA), X-ray powder diffraction (XRD), laser ablation-inductively coupled plasm-mass spectrometry (LA-ICP-MS) and Visible absorption spectrometer, in addition, its radiation safety was tested by gamma spectrometer. The results show that the refractive index and relative density of the flesh red samples are both low, with 1.54-1.55 and 2.33-2.43, while the green samples are 1.55-1.56 and 2.58-2.62; The flesh red samples contain essential mineral of clinochrysotile and auxiliary minerals of calcite and diopside, with fiber interwoven texture, fiber column-grain interwoven texture, and metamorphic residual biological skeleton texture can be seen locally; The green samples contain essential mineral of antigorite and auxiliary minerals of talc and mackinawite, with more delicate fiber interwoven texture; Elemental analysis shows that the content of Fe and Mn in flesh red samples is high, ranging from 184.9 to 951.7×10-6 and 106.4 to 287.3×10-6, respectively, while the content of Fe in green samples is very high, reaching 5,979 to 6,359×10-6. Combined with visible light absorption spectrum test, it is considered that the flesh red color caused by Fe3+, Fe2+ and Mn3+, and the green color caused by Fe2+ and Fe3+ ; The radioactivity test results indicate that the internal and external radiation indexes, and specific activity of Kuancheng serpentine jade is lower than the standard requirements, which is harmless to human body.

    参考文献
    相似文献
    引证文献
引用本文
分享
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2022-10-01
  • 最后修改日期:2023-04-21
  • 录用日期:2023-05-04
  • 在线发布日期:
  • 出版日期:
文章二维码