紫色"山仔濑石"的颜色成因及成矿机制研究
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中国地质大学珠宝学院

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国家自然科学基金(42072252);中国地质大学(武汉)珠宝检测创新中心开放基金(CIGTWZ-2022022)


Study on color origin and metallogenic mechanism of Purple "Shanzilai stone"
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Gemmological Institute,China University of Geosciences

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    摘要:

    紫色“山仔濑石”为寿山石的一种,是一种由层状硅酸盐矿物组成的粘土质玉石。其表层风化为黄色,内部为紫色,属于图章石中较为稀少的颜色品种。本文采用常规的宝石显微镜对其外观特征进行详细观察;利用X射线粉晶衍射仪、显微激光拉曼光谱仪、扫描电子显微镜、激光剥蚀等离子质谱仪等对其矿物组成、化学成分、地球化学特征及谱学特征进行测试;利用全岩化学分析、紫外-可见光分光光度计、SPSS分析模型对其颜色成因进行研究。测试结果发现紫色“山仔濑石”的主要矿物为伊利石,次要矿物为独居石、磷钡铝石、赤铁矿、重晶石;其稀土元素指示性数据呈现出轻稀土富集,重稀土亏损的现象,指示其矿物成因与还原的酸性热液蚀变有关;紫色“山仔濑石”的紫色色调深浅与主要矿物成分伊利石中锰含量高低呈现正相关性;紫色“山仔濑石”内主要矿物和次要矿物的种类、分布特征和形成温度的不同,说明在成矿后期存在热液多次侵入,所以紫色“山仔濑石”的形成过程与寿山地区的成矿规律具有一致性。

    Abstract:

    Purple “Shanzilai stone” is a kind of Shoushan stone, is a clay jade composed of layered silicate minerals. Its surface weathering for yellow, internal purple, belongs to the seal stone in the relatively rare color varieties. The appearance characteristics were studied by conventional gemstone microscope. The mineral composition, chemical composition and geochemical characteristics were studied by X-ray powder crystal diffractometer, microscopic laser Raman spectrometer, scanning electron microscope and laser denudation plasma mass spectrometer. The color origin was studied by whole rock chemical analysis, UV-visible spectrophotometer and SPSS analysis model. The results show that the main mineral of the Purple“Shanzilai stone”is Illite, and the secondary minerals are Monazite, Gorceixite, Hematite and Barite. The indicator data of REE show enrichment of LREE elements and deficit of HREE, indicating that the origin of the minerals is related to reduced acidic hydrothermal alteration. There is a positive correlation between the purple color and manganese content in Illite. The different types, distribution characteristics and formation temperatures of the main minerals and secondary minerals in Purple “Shanzilai stone” indicate that hydrothermal intrusion occurred several times in the late mineralization period, so the formation process of Purple “Shanzilai stone” is consistent with the metallogenic law in Shoushan area.

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  • 收稿日期:2022-11-01
  • 最后修改日期:2023-01-28
  • 录用日期:2023-02-03
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