黑青和田玉宝石矿物学及地球化学特征研究
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P578.955

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国家自然科学基金项目(42002156);河北省自然科学基金项目(D2021403015);河北省高等学校科学技术研究项目(QN2021027);河北地质大学国家预研项目(KY2024YB01)


Gem mineralogical and geochemical characteristics of the black cyan nephrite
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    摘要:

    近年国内市场出现了一种含有黄铁矿的黑青色玉石,主要产自新疆,属于和田玉中的稀少品种。本文利用常规宝石学仪器、偏光显微镜、红外光谱、拉曼光谱、X射线粉晶衍射(XRD)、电子探针(EPMA)、激光电感耦合等离子质谱(LA-ICP-MS)以及同位素质谱仪(MC-ICP-MS)对7块黑青和田玉样品的宝石矿物学和地球化学特征进行了系统分析,结果显示,样品颜色为墨绿-黑色,折射率点测1.61,相对密度3.08~3.17,摩氏硬度6.0~6.5,主要组成矿物为透闪石,次要矿物以黄铁矿为主,同时还含有少量绿泥石、绿帘石、榍石、锆石、石墨等,具有典型的纤维交织状结构;红外与拉曼光谱特征峰显示与和田玉标准谱峰一致;样品中透闪石的主要化学成分为SiO2、MgO、CaO和FeO,Mg/(Mg+Fe2+)值显示部分透闪石已过渡为阳起石;根据微量元素Cr-Ni投图判别样品为白云石大理岩型成因,稀土元素含量较少,呈左倾模式;推测成矿热液主要为岩浆水,含少量变质水;样品中黄铁矿Co/Ni>1且含少量As、Se、Cu、Zn、Pb等元素,δ34S介于8.87‰~20.92‰之间,推断为岩浆热液成因且硫来源于岩浆与地层硫的混合。

    Abstract:

    In recent years, a kind of black cyan nephrite containing pyrite has appeared in the domestic market. It is mainly produced in Xinjiang and belongs to a relatively rare nephrite variety, which has mining and utilization value. This article systematically analyzed the mineralogical and geochemical characteristics of seven samples using conventional gemological instruments, polarized light microscopy, infrared spectroscopy, Raman spectroscopy, X-ray powder diffraction (XRD), electron probe (EPMA) laser inductively coupled plasma mass spectrometry (LA-ICP-MS), and isotope mass spectrometer (MC-ICP-MS). The results show that the color of black cyan nephrite is dark green to black, the refractive index is 1.61, the relative density is 3.08~3.17, and the Mohs hardness is 6.0~6.5. The main component mineral is tremolite, the secondary mineral is mainly pyrite, and a small amount of chlorite, epidote, sphene, zircon, and graphite are also contained, with a typical fiber interlaced structure; The characteristic peaks of infrared and Raman spectra are consistent with the standard peaks of nephrite; The main chemical components of the sample are SiO2, MgO, CaO and FeO. The Mg/(Mg+Fe2+) value indicates that some tremolite has transitioned to actinolite. Based on the trace element Cr-Ni mapping, the sample is identified as a dolomite marble type genesis, while the content of rare earth elements is relatively low, in a left leaning mode, The ore-forming hydrothermal fluid is mainly magmatic water, containing a small amount of metamorphic water. The sample contains pyrite with Co/Ni>1 and small amounts of As, Se, Cu, Zn and Pb, δ34S ranges from 8.87‰ to 20.92‰, suggesting that it is of magmatic-hydrothermal origin and the source of sulfur is a mixture of magma and formation sulfur.

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付玉蕾,史淼,曹沁元,等, 2024. 黑青和田玉宝石矿物学及地球化学特征研究[J]. 岩石矿物学杂志, 43(3):630~642.
FU Yu-lei, SHI Miao, CAO Qin-yuan, et al, 2024. Gem mineralogical and geochemical characteristics of the black cyan nephrite[J]. Acta Petrologica et Mineralogica, 43(3): 630~642.

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  • 收稿日期:2023-12-03
  • 最后修改日期:2024-04-02
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  • 在线发布日期: 2024-05-23
  • 出版日期: 2024-05-25