粉色钻石的致色机理研究进展及其鉴定方法
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P574;P578.1+6

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广东省普通高校创新团队项目(2025KCXTD061);广东省普通高校青年创新人才项目(2022KQNCX218);广州职业技术大学科技类重大项目(2024KJ01)


Research progress on the coloration mechanism of pink diamond and its identification methods
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    摘要:

    粉色钻石因其艳丽的色彩、复杂的地质形成背景及极度稀有而备受关注,主要致色机理为550 nm吸收带(约占99%)与NV色心(约占0.6%)致色,前者见于Ⅰa及Ⅱa型,后者仅见于Ⅱa型。目前尚无法通过人工方法模拟天然塑性变形以引入550 nm吸收带,但可通过高温高压(HPHT)、辐照退火多阶段处理引入NV色心为钻石(Ⅰa型为主,Ⅱa型为辅)、合成钻石(Ⅰb-Ⅱa型、Ⅱa型)改色。部分化学气相沉积法(CVD)合成钻石中亦存在NVH与SiV色心致色。本文系统对比粉色钻石、处理钻石、合成钻石(CVD法或HPHT法制备)的宝石学与光谱学特征,提出一种基于紫外-可见光谱(UV-Vis)与红外光谱(IR)的快速鉴定方法,并结合光致发光光谱(PL)与钻石观察仪(DiamondView)实现对粉色钻石的综合鉴定。

    Abstract:

    Natural pink diamonds have attracted significant attention due to their stunning color, complex geological background, and extreme rarity. Their main coloration mechanisms include the 550 nm absorption band (accounting for approximately 99%) and NV color centers (accounting for approximately 0.6%). The former is found in Type Ⅰa and Ⅱa diamonds, while the latter only exists in Type Ⅱa diamonds. Currently, there is no artificial method capable of simulating natural plastic deformation to introduce the 550 nm absorption band. However, NV color centers can be introduced through multi-stage treatments including HPHT, irradiation and annealing, which are used for color modification of natural diamonds (predominantly Type Ⅰa, supplemented by Type Ⅱa) and synthetic diamonds (Type Ⅰb-Ⅱa and Type Ⅱa). Additionally, NVH and SiV color centers are also found in some chemical vapor deposition (CVD) synthetic diamonds. This paper systematically compares the gemological and spectroscopic characteristics of natural pink diamonds, treated natural diamonds, and synthetic diamonds (produced by CVD or HPHT methods), and proposes a rapid identification method based on ultraviolet-visible spectroscopy (UV-Vis) and infraredspectroscopy (IR). Furthermore, comprehensive identification of pink diamonds is achieved by combining photoluminescence spectroscopy (PL) and DiamondView.

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岳素伟,高诗佳,金莉莉,等, 2026. 粉色钻石的致色机理研究进展及其鉴定方法[J]. 岩石矿物学杂志, 45(2):406~426.
YUE Su-wei, GAO Shi-jia, JIN Li-li, et al, 2026. Research progress on the coloration mechanism of pink diamond and its identification methods[J]. Acta Petrologica et Mineralogica, 45(2): 406~426.

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  • 收稿日期:2024-11-20
  • 最后修改日期:2026-01-28
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  • 在线发布日期: 2026-03-17
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