A new variety of synthetic cubic zirconia: Characterization of the novel “Heavy-zircon” material
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P578.4;P575

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    Abstract:

    In 2024, a previously undocumented synthetic cubic zirconia product, traded as "heavy-zircon", emerged in the Wuzhou gem market (Guangxi, China). To address the lack of peer-reviewed data on its composition and identity, we performed a comprehensive mineralogical and gemological study using electron-probe microanalysis (EPMA), X-ray diffraction (XRD), fourier-transform infrared (FTIR), and micro-Raman spectroscopy. The material has a high relative density of approximately 7.40 and is primarily composed of Yb2O3 (51.08%~53.06%) and ZrO2, with minor Y2O3. Its elevated density results from the incorporation of ytterbium (Yb), a heavy rare earth element. Single-crystal XRD confirms an isometric fluorite-type structure (space group Fm3m) with a lattice parameter a=5.134 8(18) Å and a unit-cell volume V=135.39(8) Å3. The calculated chemical formulas are Zr0.57Yb0.40Y0.03O1.780.22 or Zr0.59Yb0.41O1.790.21 (□ denotes oxygen vacancy). These results identify heavy-zircon as a high-density, ytterbium-rich variant of yttria-stabilized cubic zirconia. In accordance with gemological nomenclature, we propose "synthetic ytterbium-rich cubic zirconia" as its formal species name.

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范桂珍,王长秋,沈才卿,覃斌荣,2025,合成立方氧化锆的新品种——“重锆”合成材料[J].岩石矿物学杂志,44(6):1464~1470. FAN Gui-zhen, WANG Chang-qiu, SHEN Cai-qing, QIN Bin-rong,2025,A new variety of synthetic cubic zirconia: Characterization of the novel “Heavy-zircon” material[J]. Acta Petrologica et Mineralogica,44(6):1464~1470.

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History
  • Received:June 01,2025
  • Revised:September 28,2025
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  • Online: November 21,2025
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